PokerTracker 4 doesn't have "vs hero" stats built in but it can be done with custom stats. You can search our forums for examples and there is a thread on this topic
here. Some of our Premium partners (like PokerProHuds among others) may also sell these kinds of stats although I do not have a full list available for that. See
this guide for the basics on custom statistics creation and
this guide for a deeper walkthrough. The latter was written for PokerTracker 3 but the techniques all apply to PokerTracker 4, the interface is just slightly different.